Hossein Behniafar, Ali Beit-Saeed, Ahmad Hadian
Polym Degrad Stabil 94, 1991–1998 (2009)
Publication year: 2009
In this research, a new diimide-diacid monomer, 2,2′-bis(4-phenoxyphenyl)-4,4′-bis(N-trimellitoyl)diphenyl ether (BPDPE) containing two laterally-attached phenoxy phenylene groups was prepared by the reaction of 2,2′-bis[(p-phenoxy phenyl)]-4,4′-diaminodiphenyl ether (PPAPE) with trimellitic anhydride in refluxing glacial acetic acid. Ether-hinged wholly aromatic poly(amide-imide)s with limited viscosity number values of 0.61–0.87 dL g-1 were prepared by triphenyl phosphate (TPP)-activated polycondensation of BPDPE with diamines including PPAPE and 4,4′-diaminodiphenyl ether (DADPE). For comparative purposes, reference poly(amide-imide)s were also prepared by reacting diimide-diacid monomer lacking phenoxy phenylene lateral groups namely 4,4′-bis(N-trimellitoyl)diphenyl ether (BTDPE) with the same diamines under similar conditions. A model compound MODEL was also synthesized by the reaction of BTBPE with two mole equivalents of aniline to compare the spectral characteristics results. Number and weight average molecular weights were determined by gel permeation chromatography (GPC) technique. The phenoxy phenylene-containing poly(amideimide)s (all, except that of resulted from BTDPE and DADPE) had excellent organosolubility in common polar solvents. A low crystallinity extent was only observed using their wide-angle X-ray diffractograms (WAXD). A qualitative study showed the prepared polymers could also be cast into optically-transparent and flexible thin films. The ether-containing lateral groups attached to the ether-hinged macromolecular main chains had no substantial diminishing effect on the thermal stability of these structurally-modified poly(amide-imide)s.